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61.
Yousof?Mardoukhi Esa?R?s?nenEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2014,87(6):144
Semiconductor quantum dots are among the leading candidates for next-generation nanoscale devices due to their tunable size, shape, and low energy consumption. Here we apply quantum optimal control theory to coherently manipulate the single-electron charge distribution in quantum-dot lattices of various sizes. In particular, we show that to control the charge distribution it is sufficient to optimize the gate voltage acting on a single quantum dot in the lattice. We generally find yields around 99% in the picosecond time scale when using realistic models for the quantum-dot lattices on a real-space grid. We analyze and discuss both the limitations of the model regarding the gate parameters as well as the potential of the scheme for applications as quantum-dot cellular automata. 相似文献
62.
Shankaran Sundarajoo Emad L. Izake William Olds Biju Cletus Esa Jaatinen Peter M. Fredericks 《Journal of Raman spectroscopy : JRS》2013,44(7):949-956
Time‐resolved Raman spectroscopy, spatially offset Raman spectroscopy and time‐resolved spatially offset Raman spectroscopy (TR‐SORS) have proven their capability for the non‐invasive profiling of deep layers of a sample. Recent studies have indicated that TR‐SORS exhibits an enhanced selectivity toward the deep layers of a sample. However, the enhanced depth profiling efficiency of TR‐SORS, in comparison with time‐resolved Raman spectroscopy and spatially offset Raman spectroscopy, is yet to be assessed and explained in accordance to the synergistic effects of spatial and temporal resolutions. This study provides a critical investigation of the depth profiling efficiency of the three deep Raman techniques. The study compares the efficiency of the various deep Raman spectroscopy techniques for the stand‐off detection of explosive precursors hidden in highly fluorescing packaging. The study explains for the first time the synergistic effects of spatial and temporal resolutions in the deep Raman techniques and their impact on the acquired spectral data. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
63.
Esa T. T. Kumpulainen Ari M. P. Koskinen Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(41):10901-10911
The influence of catalyst components in the copper–TEMPO (2,2,6,6‐tetramethylpiperidine N‐oxide) catalysed aerobic oxidation of alcohols was investigated. The type and amount of base greatly influences reactivity. The bipyridyl ligand concentration had no major influence on catalysis, but excessive amounts led to a decrease in activity for longer reaction times. The kinetic dependency for TEMPO was found to be 1.15, and for copper 2.25, which is an indication of a binuclear catalytic system. Optimised conditions with various allylic and aliphatic alcohols give good to excellent rapid oxidations. 相似文献
64.
Esa Jä rvenpä ä Maarit Jä rvenpä ä 《Proceedings of the American Mathematical Society》2002,130(2):419-426
We study dimensional properties of porous measures on . As a corollary of a theorem describing the local structure of nearly uniformly porous measures we prove that the packing dimension of any Radon measure on has an upper bound depending on porosity. This upper bound tends to as porosity tends to its maximum value.
65.
We derive sufficient conditions for ∝ λ (dx)6Pn(x, ·) - π6 to be of order o(ψ(n)-1), where Pn (x, A) are the transition probabilities of an aperiodic Harris recurrent Markov chain, π is the invariant probability measure, λ an initial distribution and ψ belongs to a suitable class of non-decreasing sequences. The basic condition involved is the ergodicity of order ψ, which in a countable state space is equivalent to for some i, where τi is the hitting time of the tate i. We also show that for a general Markov chain to be ergodic of order ψ it suffices that a corresponding condition is satisfied by a small set.We apply these results to non-singular renewal measures on providing a probabilisite method to estimate the right tail of the renewal measure when the increment distribution F satisfies ∝ tF(dt) 0; > 0 and ∝ ψ(t)(1- F(t))dt< ∞. 相似文献
66.
Esa Nummelin 《Journal of statistical physics》1994,75(5-6):879-889
We show that under the Bernoulli initial condition two kinks in the cellular automaton (CA) 18/256 will annihilate each other with probability one. It turns out that there is an equivalent statement in terms of percolation in the simple binary additive CA. Namely, under the Bernoulli initial condition, l's do not percolate in the binary additive CA. 相似文献
67.
Dev?Chandra Esa?R?Korpi Celia?P?Miralles Angel?L?De Blas Gregg?E?HomanicsEmail author 《BMC neuroscience》2005,6(1):30
Background
Gamma-aminobutyric acid type A receptors (GABAA-Rs) are the major inhibitory receptors in the mammalian brain and are modulated by a number of sedative/hypnotic drugs including benzodiazepines and anesthetics. The significance of specific GABAA-Rs subunits with respect to behavior and in vivo drug responses is incompletely understood. The γ2 subunit is highly expressed throughout the brain. Global γ2 knockout mice are insensitive to the hypnotic effects of diazepam and die perinatally. Heterozygous γ2 global knockout mice are viable and have increased anxiety-like behaviors. To further investigate the role of the γ2 subunit in behavior and whole animal drug action, we used gene targeting to create a novel mouse line with attenuated γ2 expression, i.e., γ2 knockdown mice. 相似文献68.
Esa ?J?rvenp??Email author Maarit?J?rvenp?? Mika?Leikas 《Communications in Mathematical Physics》2005,254(3):695-717
We show that, unlike in the 2-dimensional case [LL], the Hausdorff dimension of a measure invariant under the geodesic flow is not necessarily preserved under the projection from the unit tangent bundle onto the base manifold if the base manifold is at least 3-dimensional. In the 2-dimensional case we reprove the preservation theorem due to Ledrappier and Lindenstrauss [LL] using the general projection formalism of Peres and Schlag [PS]. The novelty of our proof is that it illustrates the reason behind the failure of the preservation in the higher dimensional case. Finally, we show that the projected measure has fractional derivatives of order for all <(–2)/2 provided that the invariant measure has finite -energy for some >2 and the base manifold has dimension 2.MJ and ML acknowledge the support of the Academy of Finland, project #48557.Acknowledgement. We thank the referee for valuable comments clarifying the exposition. 相似文献
69.
Koskinen AM Helaja J Kumpulainen ET Koivisto J Mansikkamäki H Rissanen K 《The Journal of organic chemistry》2005,70(16):6447-6453
The motional restrictions of the proline pyrrolidine ring allow this secondary amine amino acid to act as a turn inducer in many peptides and proteins. The pyrrolidine ring is known to exhibit two predominant pucker modes (i.e., C-4 (Cgamma) exo and endo envelope conformers whose ratio can be controlled by proper substituents in the ring). In nature, the exo puckered 4(R)-hydroxy-l-proline plays a crucial role as a building block in collagen and collagen-like structures. It has been previously concluded that the electronegativity of the 4-cis-substituent increases the endo puckering while the electronegativity of the 4-trans-substituent favors the exo puckering. Here, we have introduced a sterically demanding tert-butyl group at C-4 in trans- and cis-configurations. In the case of trans-substitution, the induced puckering effect on the pyrrolidine ring was studied with X-ray crystallography and 1H NMR spectral simulations. Both cis- and trans-4-tert-butyl groups strongly favor pseudoequatorial orientation, thereby causing opposite puckering effects for the pyrrolidine ring, cis-exo and trans-endo for l-prolines, in contrast to the effects observed in the case of electronegative C-4 substituents. The syntheses and structural analysis are presented for the conformationally constrained 4-tert-butylprolines. The prolines were synthesized from 4-hydroxy-l-proline, substitution with t-BuCuSPhLi being the key transformation. This reaction gave N-Boc-trans-4-tert-butyl-l-proline tert-butyl ester in 94% ee and 57% de. Enantioselectivity was increased to 99.2% ee by crystallization of N-Boc-trans-4-tert-butyl-l-proline in the final step of the synthesis. 相似文献
70.